Effect of cocoa fat content on wetting and surface energy of chocolate

  • Lubomír Lapčík Department of Food Technology, Faculty of Technology. Tomas Bata University in Zlín, Vavrečkova 275, 762 72 Zlín
  • Barbora Lapčíková Department of Food Technology, Faculty of Technology. Tomas Bata University in Zlín, Vavrečkova 275, 762 72 Zlín
  • Hana Žižková Department of Food Technology, Faculty of Technology. Tomas Bata University in Zlín, Vavrečkova 275, 762 72 Zlín
  • Peng Li Department of Food Technology, Faculty of Technology. Tomas Bata University in Zlín, Vavrečkova 275, 762 72 Zlín
  • Viera Vojtekova Institute of chemistry, Pavol Jozef Safarik University in Košice, Moyzesova 11, 040 01 Košice
Keywords: chocolate, cocoa fat, surface energy, wetting

Abstract

The aim of this study was the quantification of the effect of the cocoa fat content on the wetting characteristics and surface free energy of different chocolate compositions. On the market, there are many different types of chocolate products which differ both in the sensory and physico-chemical properties together with their raw material compositions and the contents of the individual components. This paper focuses on differences in the use of different types of fats - cocoa butter, milk fat, equivalents or cocoa butter substitutes in chocolate products. Studied samples (prepared at Carla, Ltd. Company) were followed by static contact angles of wetting measurements and by calculated surface free energies. There were investigated the effects of fat content and used fat types of the chocolate products on their final wettabilities and resulting surface free energies. There was found a linear dependence between total fat content and the surface free energy, which was gradually increasing with increasing fat content. Additionally, there were performed TG DTG and NIR spectrometry measurements of the tested materials with the aim to determine the melting point of studied fats used, as well as to determine and identify individual fat components of chocolate products which may affect the resulting value of surface free energy.

References

Beckett. S. T. 2008. The science of chocolate. 2nd ed. Cambridge, UK : RSC Publishing. 240 p. ISBN 0854049703.


Briones, V., Aguilera, J. M. 2005. Image analysis of changes in surface color of chocolate. Food Research International, vol. 38, no. 1, p. 87-94. doi:http://dx.doi.org/10.1016/ j.foodres.2004.09.002

 

Gajdošíková, R., Lapčíková, B., Lapčík, L. 2011. Surface phenomena and wetting of porous solids. Physical Chemistry, vol. 6, no. 3, p. 146-162.

 

Godočiková, L., Ivanišová, E., Árvay, J., Petrová, J., Kačániová, M. 2016. The comparison of biological activity of chocolates made by different technological procedures. Potravinarstvo, vol. 10, no. 1, p. 316-322. doi:http://dx.doi.org/10.5219/628

 

Keijbets, E. L., Chen, J., Dickinson, E., Vieira, J. 2009. Surface energy investigation of cololate adhesion to solid mould materials. Journal of Food Engineering, vol. 92, no. 2, p. 217-225. doi:http://dx.doi.org/10.1016/j.jfoodeng.2008.11.008

 

Kinta, Y., Hatta, T. 2005. Composition and structure of fat bloom in untempered chocolate. Journal of Food Science, vol. 70, no. 7, p. S450-S452.

 

Lapčík, L., Lapčíková, B., Otyepková, E., Otyepka, M., Vlček, J., Buňka, F., Salek R. N. 2015. Surface energy analysis (SEA) amd rheology of powder milk dairy products. Food Chemistry, vol. 174, p. 25-30. doi:http://dx.doi.org/10.1016/ j.foodchem.2014.11.017

 

Lapčík, L., Otyepka, K., Otyepková, E., Lapčíková, B., Gabriel, R., Gavenda, A., Prudilová, B. 2016. Surface heterogeneity: Information from inverse gas chromatography and application to model pharmaceutical substances. Current Opinion in Colloid & Interface Science, vol. 24, p. 64-71. doi:http://dx.doi.org/10.1016/j.cocis.2016.06.010

 

Machálková, L., Hřivna, L., Nedomová, Š., Jůzl, M. 2015. The effect of storage temperature on the quality and formation of blooming defects in chocolate confectionery. Potravinarstvo, vol. 9, no. 1, p. 39-47. doi:http://dx.doi.org/10.5219/425

Published
2017-06-19
How to Cite
Lapčík, L., Lapčíková, B., Žižková, H., Li, P., & Vojtekova, V. (2017). Effect of cocoa fat content on wetting and surface energy of chocolate. Potravinarstvo Slovak Journal of Food Sciences, 11(1), 410-416. https://doi.org/10.5219/732